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Of molten copper or molten and on the concave side of the meniscus. Thus,cadmium, the surface tension increases with the pressure on the concave side i.e., inside theincrease in its temperature. liquid is greater than that on the convex side i.e., outside the liquid. The surface tension of a liquid becomes c) Concave liquid surface:zero at critical temperature.2.4.5 Excess pressure across the free surface Fig. 2.21 (c): Concave Surface.of a liquid: Surface of the liquid in the Fig. 2.21 (c) is upper concave (concave, when seen from Every molecule on a liquid surface above). In this case, the force due to surfaceexperiences forces due to surface tension tension fT , on the molecule at B is verticallywhich are tangential to the liquid surface at upwards. The force f A due to atmosphericrest. The direction of the resultant force of pressure acts downwords. Forces f A and fTsurface tension acting on a molecule on the thus, act in opposite direction. Therefore,liquid surface depends upon the shape of that the net downward force responsible for theliquid surface. This force also contributes in pressure at B is less than f A . This develops adeciding the pressure at a point just below the lesser pressure at point B, which is inside thesurface of a liquid. liquid and on the convex side of the meniscus. Thus, the pressure on the concave side i.e., Figures 2.21 (a), (b) and (c) show surfaces outside the liquid, is greater than that on theof three liquids with different shapes and their convex side, i.e., inside the liquid.menisci. Let f A be the downward force due to 2.4.6 Explanation of formation of drops andthe atmospheric pressure. All the three figures bubbles:show two molecules A and B. The molecule A Liquid drops and small bubbles areis just above, and the molecule B is just below spherical in shape because the forces of surfaceit (inside the liquid). Level difference between tension dominate the gravitational force.A and B is almost zero, so that it does not These force always try to minimize the surfacecontribute anything to the pressure difference. area of the liquid. A bubble or drop does notIn all the three figures, the pressure at the point collapse because the resultant of the externalA is the atmospheric pressure p. pressure and the force of surface tension isa) Plane liquid surface: smaller than the pressure inside a bubble or inside a liquid drop. Figure 2.21 (a) shows planar free surfaceof the liquid. In this case, the resultant forceidsuzeetroo.suTrhfeacfeortceensifoAni,tsfeTlfodnecthideems tohleecpurleessautrBeand the pressure at A and B is the same. Fig. 2.21 (a): Plane surface.b) Convex liquid surface: Surface of the liquid in the Fig.2.21 (b)is upper convex. (Convex, when seen fromabove). In this case, the resultant force dueto surface tension, fT on the molecule at Bis vertically downwards and adds up to the 40Consider a spherical drop as shown in surface and the outer surface. For a bubble,Fig. 2.22. Let pi be the pressure inside the dropand p0 be the pressure out side

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Is N/m. Its Dimensionsphere of influence that lies within the liquid. are, [L0M1T-2].This is because, the density of air is less thanthat of a liquid. The adhesive force trying to Use your brain powerpull the molecule above the liquid surface ismuch weaker than the cohesive force that tries Prove that, equivalent S.I. unit of surfaceto pull the molecule inside the liquid surface. tension is J/m2.As a result, the molecule C also gets attractedinside the liquid. Example 2.4: A beaker of radius 10 cm Thus, all molecules in the surface film is filled with water. Calculate the forceare acted upon by an unbalanced net cohesiveforce directed into the liquid. Therefore, the of surface tension on any diametrical linemolecules in the surface film are pulled insidethe liquid. This minimizes the total number of on its surface. Surface tension of water ismolecules in the surface film. As a result, thesurface film remains under tension. The surface 0.075 N/m.film of a liquid behaves like a stretched elasticmembrane. This tension is known as surface Solution: Given,tension. The force due to surface tension actstangential to the free surface of a liquid. L = 2 × 10 = 20 cm = 0.2 m2.4.2 Surface Tension and Surface Energy:a) Surface Tension: As seen previously, the T = 0.075 N/mfree surface of a liquid in a container acts asa stretched membrane and all molecules on We have, = FLthe surface film experience a stretching force.Imagine a line PQ of length L drawn tangential Tto the free surface of the liquid, as shown in Fig. 2.16. ∴F = TL = 0.075 × 0.2 = 0.015 = 1.5 × 10-2 N Table 2.1 – Surface tension of some liquids at 20oC. Sr. Liquid S.T. S.T. No. (N/m) (dyne/cm) 0.0727 1 Water 0.4355 72.7 0.025 435.5 2 Mercury 25 3 Soap solution 4 Glycerin 0.0632 63.2 Fig. 2.16: Force of surface tension. b) Surface Energy: We have seen that a molecule inside the volume of a liquid (like All the molecules on this line experience molecule A in Fig 2.15) experiences moreequal and opposite forces tangential to surface cohesive force than a molecule like moleculesas if they are tearing the surface apart due B and C in the surface film of the liquid into the cohesive forces of molecules lying on that figure. Thus, work has to be done to bringeither side. any molecule from inside the liquid into the surface film. Clearly, the surface molecules possess extra potential energy as compared to the molecules inside the liquid. The extra 35energy of the molecules in the surface layer opposite to F) applied isothermally (graduallyis called the surface energy of the liquid. As and at constant temperature), to the armany system always tries to attain a state of QR, so that it pulls the arm away and triesminimum potential energy, the liquid tries to to increase the surface area of the film. Thereduce the area of its surface film. Energy has arm QR moves to Q′R′ through a distance dx.to be spent in